Resumen
Recent investigations showed that bromine is incorporated to soil organic matter (SOM), its content increasing with humification. But few research was done on its long-term accumulation and the role played by pedogenetic processes, as those involved in organic matter stabilization. We investigated bromine content and distribution in four deep, acidic, organic-rich, Holocene soils from an oceanic area of Western Europe. Bromine concentrations (93–778 μg g−1) in the silt + clay (<50 μm) fraction were on average 3-times higher than those (17–250 μg g−1) in the fine earth (<2 mm), the former containing almost all bromine (90 ± 5%). Inventories were between 148 and 314 g m−2, indicating a rather large variability in a small area, and total estimated retention was low (6–16%). The degree of SOM bromination, expressed as the Br/C molar ratio, varied between 0.03 and 1.20 mmol Br/mol C. The ratio was highly correlated (n = 23, r2 0.88, p < 0.01) with the age of the SOM for the last ∼12 ka. Partial least squares modeling indicates that bromine concentration depends on the amount of organic matter stabilized as aluminium-OM associations, and to a lesser extent on soil acidity (pH) and iron-OM associations. Thus, at scales of thousands of years, bromine accumulation in acidic soils is linked to the pool of metal–clay-stabilized organic matter.
